2-Amino-N′-phenylbenzohydrazide
نویسندگان
چکیده
In the title compound, C(13)H(13)N(3)O, the NNCO unit forms dihedral angles of 35.8 (1) and 84.0 (1)° with the benzene and phenyl rings, respectively. The dihedral angles between the aromatic rings is 61.2 (1)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, mol-ecules are linked by weak N-H⋯O hydrogen bonds into C(4) chains parallel to the c axis. Neighbouring chains are linked by weak N-H⋯N hydrogen bonds, forming R(4) (4)(20) rings, and resulting in the formation of a two-dimensional network lying parallel to (010). The packing also features π-π stacking inter-actions between phenyl rings [centroid-centroid distance = 3.803 (2) Å].
منابع مشابه
N′-(3-Methylquinoxalin-2-yl)-N′-phenylbenzohydrazide
In the crystal structure of the title compound, C(22)H(18)N(4)O, the quinoxaline system makes dihedral angles of 86.59 (7) and 63.37 (9)° with the benzohydrazide and phenyl rings, respectively. The benzohydrazide ring makes a dihedral angle of 72.46 (10)° with the phenyl ring. The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds, C-H⋯O contacts and C-H⋯π inter-actions.
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